Despite decades of regulation, nitrogen pollution remains one of the most challenging and costly environmental problems globally.
Nitrate and nitrite occur as natural stages of the nitrogen cycle and are essential components of the molecular building blocks for plant life and growth.
But intensive human activity has thrown the nitrogen cycle out of balance.
We are ‘overfeeding’ our aquatic systems with excessive nitrogen-based nutrients from agricultural runoff and sewage effluent, entering our rivers, lakes and estuaries, and excess fertilisers and manure seeping into our groundwater.
The environmental impacts of nitrate pollution include ecological and amenity damage to our rivers, lakes and coasts; higher costs, energy use and carbon emissions for drinking water treatment and long-term impacts for our groundwater.
Impacts for rivers, lakes and coastal waters
When effluent from wastewater treatment plants or runoff from agricultural sources, septic tanks or stormwater enter the aquatic environment, they introduce nutrient-rich nitrate and nitrite (a process known as eutrophication).
This enrichment can promote a growth explosion of algae and phytoplankton, manifest as unsightly, often offensive-smelling scum or ‘algal blooms’ on the water surface.
Some blooms, known as harmful algal blooms, also secrete toxins, making drinking water sources unsafe, poisoning fish and the marine bird and mammals that feed off them and creating ‘dead zones’ where no life can survive.
However, the term ‘harmful’ to when just applied to toxin-emitting blooms is somewhat misleading, since all algal blooms are potentially harmful. Universal impacts include the risk of ecological damage as the dense growth blocks sunlight, and, as it decomposes, it starves aquatic species of oxygen.
Not only that but nitrogen-fuelled algal blooms also impact lifestyles, tourism and economies, as they limit the use of lakes, rivers and estuaries for swimming, boating and fishing.
The threat to safe drinking water
Harmful algal blooms, and their toxic effects, are just one issue for water producers…
Health concerns about nitrate also arise because of its conversion to nitrite within the human body.
Associated with a condition known as methaemoglobinaemia, nitrite effects the blood’s ability to transport oxygen, and, as a result, can lead to unconsciousness and even death. Because methaemoglobinaemia is far more common in infants than in older children or adults, it is sometimes known as ‘blue baby syndrome’.
For health protection, EU regulators have limited the maximum allowable concentrations to 50 mg/l for nitrate and just 0.5 mg/l for nitrite in drinking water and groundwater. In the US, the limits are roughly similar.
To achieve these standards, however, public utilities and water companies in nitrate-stressed regions must invest millions in energy-intensive nitrate removal processes, water blending plants and catchment management programmes. Ultimately, the consumer picks up the tab.
The situation is at least as troubling for private water supply users. The World Health Organisation reports that recent cases of methaemoglobinaemia have most frequently been associated with private well use. But equally, the monitoring and enforcement of nitrate and nitrite limits in private supplies is more challenging for regulators and typically less rigorous.
Environmental impacts of nitrate in ground water – the time bomb beneath our feet
When nitrogen sources leach below the soil surface and oxygen is present, they convert to nitrate. Nitrate contaminated groundwater is prevalent today in intensively farmed and fertilised regions throughout the world.
Initially shallow aquifers are at greatest risk. However, where the water table is deeper, a longer term problem is brewing. Slower to percolate through the thicker sub-surface, large nitrate stores have built up as a result of decades of intensive fertiliser application. Scientists estimate that up to 180 million tonnes of nitrate are stored in rocks worldwide – perhaps twice the amount stored in soils. They warn that this phenomenon, dubbed the “nitrate time bomb” will continue to impact water quality for decades. As a result, the bill for additional water treatment may amount to billions, and aquifer-fed wetlands and rivers will continue to suffer from eutrophication and amenity and species loss.
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How Aquamonitrix is different from existing nitrate and nitrite analysers
This video illustrates how Aquamonitrix® is a revolutionary new autonomous, real-time analyser for simultaneously measuring nitrate and nitrite in situ in fresh and effluent water.
